It sounds like he tried stopping the car with the brakes while it was still driving the wheels. Without specific mechanical forensics data, though, there is no way to know for sure.
As a general rule, to avoid confusion and inaction, you always want to disengage the driveline first. Then any other problems that arise are easier to handle without having to wrestle a speeding car.
A lot of crashes, and deaths, could be avoided if we just taught drivers to think ahead when behind the wheel, instead of the terrible 'defensive driving' they teach in Driver's Ed. Defensive driving becomes reactive driving, so no one has any idea what to do when they have to act. For example, in heavy traffic, I am always braking before the car in front of me, because I look down the road. I can still see him, but already know what he's going to do based on the cars in front. Even people who think they are good drivers don't anticipate and plan ahead.
Everyone should take their car out somewhere safe like a giant parking lot and practice stopping under no power. It will build the instinct to act if it ever does happen.